I would wager that there is no clear cut answer to whether going from say a 225/45 to a 245/40 is "better" on a 7" wheel. What would work better on one car/suspension setup might be worse on a different one.
Two main things are at work on wheel widths/tire sizes: (1) tire sidewall spring rate, and (2) tire contact patch nature under load, dynamic and quasi-steady state.
Increasing section width for a fixed wheel width generally reduces sidewall spring rate hence the comments about such feeling gooey or less precise, etc. Reducing sidewall spring rate can influence the car's balance during transient conditions, slalom, turn-in, etc, typically creating more rotation as the tail is more sensitive, and it also makes the car less responsive to rapid inputs. Invert this behavior for wide wheels. It feels great to drive the same car/tires when you bump up wheel width -- responsive, better feel for the contact patch, etc.
The 2nd part, the contact patch nature, means what is the character of the tire to road contact patch during all conditions, from violent transient inputs all the way to almost steady state conditions like the middle of a long sweeper. This part is likely very important for maximum grip, and I have no clear answer since I think it would heavily depend on all the variables (specific tire carcass/sidewall design, air pressure, suspension design (i.e. great camber under load vs poor camber under load), etc, etc).
Hence my thought that on a given car/suspension setup, the 225/7" combo might time out quicker/slower than the 245/7" combo. I've always wanted to see carefully instrumented tests like this (and I mean wanted to for many years, as in 30+) where you would take the same car/tire and use the minimum wheel width and the maximum wheel width. Evaluate slalom, skidpad and road course performance (double blind tests). Do this for two significantly different tire designs (i.e. a Hoosier A6 might yield significantly different results than a Kumho V710 for example) and two completely different cars (perhaps stock suspension FWD versus a nicely setup RWD).
I've just blathered this all of the top of my head, so I know I've left a lot out -- this is (can be) a very complicated analysis/test (or at the very least I'm capable of making it very complicated,

).